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Numerical Simulation of Gas Phase Reaction for Epitaxial Chemical Vapor Deposition of Silicon Carbide by Methyltrichlorosilane in Horizontal Hot-Wall Reactor
| Content Provider | MDPI |
|---|---|
| Author | Song, Botao Gao, Bing Han, Pengfei Yu, Yue Tang, Xia |
| Copyright Year | 2021 |
| Description | Methyltrichlorosilane $(CH_{3}SiCl_{3}$, MTS) has good performance in stoichiometric silicon carbide (SiC) deposition and can be facilitated at relatively lower temperature. Simulations of the chemical vapor deposition in the two-dimensional horizontal hot-wall reactor for epitaxial processes of SiC, which were prepared from $MTS-H_{2}$ gaseous system, were performed in this work by using the finite element method. The chemistry kinetic model of gas-phase reactions employed in this work was proposed by other researchers. The total gas flow rate, temperature, and ratio of $MTS/H_{2}$ were the main process parameters in this work, and their effects on consumption rate of MTS, molar fraction of intermediate species and C/Si ratio inside the hot reaction chamber were analyzed in detail. The phenomena of our simulations are interesting. Both low total gas flow rate and high substrate temperature have obvious effectiveness on increasing the consumption rate of MTS. For all cases, the highest three C contained intermediates are $CH_{4}$, $C_{2}H_{4}$ and $C_{2}H_{2}$, respectively, while the highest three Si/Cl contained intermediates are $SiCl_{2}$, $SiCl_{4}$ and HCl, respectively. Furthermore, low total gas flow results in a uniform C/Si ratio at different temperatures, and reducing the ratio of $MTS/H_{2}$ is an interesting way to raise the C/Si ratio in the reactor. |
| Starting Page | 7532 |
| e-ISSN | 19961944 |
| DOI | 10.3390/ma14247532 |
| Journal | Materials |
| Issue Number | 24 |
| Volume Number | 14 |
| Language | English |
| Publisher | MDPI |
| Publisher Date | 2021-12-08 |
| Access Restriction | Open |
| Subject Keyword | Materials Chemical Vapor Deposition Gas Phase Reaction Mts/h2 Ratio Numerical Model |
| Content Type | Text |
| Resource Type | Article |
