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A Tetranuclear Dysprosium Schiff Base Complex Showing Slow Relaxation of Magnetization
| Content Provider | MDPI |
|---|---|
| Author | Cyril, Rajnák Roman, Boča Gebrezgiabher, Mamo Schlittenhardt, Sören Sergawie, Assefa Ruben, Mario Thomas, Madhu |
| Copyright Year | 2022 |
| Description | A tetranuclear dysprosium Schiff base complex was isolated by reacting dysprosium chloride with 2-hydroxy-3-methoxybenzaldehyde and 2-(aminomethyl)pyridine in-situ under basic conditions. The isolated Dy(III) complex was characterized by elemental analyses, single crystal X-ray diffraction and molecular spectroscopy. The complex crystallizes in the triclinic space group P-1 with unit cell parameters of a = 10.2003 (4), b = 13.8602 (5), c = 14.9542 (6), α = 94.523 (3), β = 109.362 (4), and γ = 99.861 (3). The magnetic properties of 1 have been investigated by DC and AC susceptibility measurements. The DC measurements reveal weak exchange coupling of antiferromagnetic nature. In the AC measurement, the complex shows a slow relaxation of magnetization in the absence of an external magnetic field. |
| Starting Page | 66 |
| e-ISSN | 23046740 |
| DOI | 10.3390/inorganics10050066 |
| Journal | Inorganics |
| Issue Number | 5 |
| Volume Number | 10 |
| Language | English |
| Publisher | MDPI |
| Publisher Date | 2022-05-21 |
| Access Restriction | Open |
| Subject Keyword | Inorganics Schiff Base Dysprosium Complex X-ray Structure Slow Magnetic Relaxation |
| Content Type | Text |
| Resource Type | Article |
