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Comparison of Plasma Deposition of Carbon Nanomaterials Using Various Polymer Materials as a Carbon Atom Source
| Content Provider | MDPI |
|---|---|
| Author | Miran, Mozetič Vesel, Alenka Zaplotnik, Rok Primc, Gregor Paul, Domen |
| Copyright Year | 2022 |
| Description | Carbon nanowalls are promising materials for various electrochemical devices due to their chemical inertness, desirable electrical conductivity, and excellent surface-to-mass ratio. Standard techniques, often based on plasma-assisted deposition using gaseous precursors, enable the synthesis of top-quality carbon nanowalls, but require long deposition times which represents a serious obstacle for mass applications. Here, an alternative deposition technique is presented. The carbon nanowalls were synthesized on titanium substrates using various polymers as solid precursors. A solid precursor and the substrate were mounted into a low-pressure plasma reactor. Plasma was sustained by an inductively coupled radiofrequency discharge in the H-mode at the power of 500 W. Spontaneous growth of carbon nanomaterials was observed for a variety of polymer precursors. The best quality of carbon nanowalls was obtained using aliphatic polyolefins. The highest growth rate of a thin film of carbon nanowalls of about 200 nm/s was observed. The results were explained by different degradation mechanisms of polymers upon plasma treatment and the surface kinetics. |
| Starting Page | 246 |
| e-ISSN | 20794991 |
| DOI | 10.3390/nano12020246 |
| Journal | Nanomaterials |
| Issue Number | 2 |
| Volume Number | 12 |
| Language | English |
| Publisher | MDPI |
| Publisher Date | 2022-01-13 |
| Access Restriction | Open |
| Subject Keyword | Nanomaterials Carbon Nanowalls Plasma Deposition Fast Synthesis One-step Procedure Polymer Source |
| Content Type | Text |
| Resource Type | Article |