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Bis(Dicarbollide) Complexes of Transition Metals as a Platform for Molecular Switches. Study of Complexation of 8,8′-Bis(Methylsulfanyl) Derivatives of Cobalt and Iron Bis(Dicarbollides)
| Content Provider | MDPI |
|---|---|
| Author | Anufriev, Sergey A. Timofeev, Sergey V. Anisimov, Alexei A. Suponitsky, Kyrill Yu. Sivaev, Igor B. |
| Copyright Year | 2020 |
| Description | Complexation of the 8,8′-bis(methylsulfanyl) derivatives of cobalt and iron bis(dicarbollides) [8,8′-(MeS)2-3,3′-M(1,2-C2B9H10)2]− (M = Co, Fe) with copper, silver, palladium and rhodium leads to the formation of the corresponding chelate complexes, which is accompanied by a transition from the transoid to the cisoid conformation of the bis(dicarbollide) complex. This transition is reversible and can be used in design of coordination-driven molecular switches based on transition metal bis(dicarbollide) complexes. The solid-state structures of {(Ph3P)ClPd[8,8′- (MeS)2-3,3′-Co(1,2-C2B9H10)2-κ2-S,S′]} and {(COD)Rh[8,8′-(MeS)2-3,3′-Co(1,2-C2B9H10)2-κ2-S,S′]} were determined by single crystal X-ray diffraction. |
| Starting Page | 5745 |
| e-ISSN | 14203049 |
| DOI | 10.3390/molecules25235745 |
| Journal | Molecules |
| Issue Number | 23 |
| Volume Number | 25 |
| Language | English |
| Publisher | MDPI |
| Publisher Date | 2020-12-05 |
| Access Restriction | Open |
| Subject Keyword | Molecules Inorganic Chemistry Molecular Switches Cobalt Bis(dicarbollide) Iron Bis(dicarbollide) Methylsulfanyl Derivatives Complexation X-ray Diffraction |
| Content Type | Text |
| Resource Type | Article |
