NDLI: Phase Transitions and Electrochemical Properties of Ionic Liquids and Ionic Liquid

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Phase Transitions and Electrochemical Properties of Ionic Liquids and Ionic Liquid—Solvent Mixtures

Content Provider	MDPI
Author	Cruz, Carolina Ciach, Alina
Copyright Year	2021
Description	Recent advances in studies of ionic liquids (IL) and ionic liquid–solvent mixtures are reviewed. Selected experimental, simulation, and theoretical results for electrochemical, thermodynamical, and structural properties of IL and IL-solvent mixtures are described. Special attention is paid to phenomena that are not predicted by the classical theories of the electrical double layer or disagree strongly with these theories. We focus on structural properties, especially on distribution of ions near electrodes, on electrical double layer capacitance, on effects of confinement, including decay length of a dissjoining pressure between confinig plates, and on demixing phase transition. In particular, effects of the demixing phase transition on electrochemical properties of ionic liquid–solvent mixtures for different degrees of confinement are presented.
Starting Page	3668
e-ISSN	14203049
DOI	10.3390/molecules26123668
Journal	Molecules
Issue Number	12
Volume Number	26
Language	English
Publisher	MDPI
Publisher Date	2021-06-16
Access Restriction	Open
Subject Keyword	Molecules Physical Chemistry Ionic Liquids Ionic Liquid-solvent Mixtures Demixing Phase Transition Effects of Confinement in Ionic Systems Differential Capacitance Electrical Double Layer Supercapacitors
Content Type	Text
Resource Type	Article

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