NDLI: Development of Amine-Functionalized Metal-Organic Frameworks Hollow Fiber Mixed Matrix Membranes for $CO_{2}$ and $CH_{4}$ Separation: A Review

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Development of Amine-Functionalized Metal-Organic Frameworks Hollow Fiber Mixed Matrix Membranes for $CO_{2}$ and $CH_{4}$ Separation: A Review

Content Provider	MDPI
Author	Sunder, Naveen Fong, Yeong Yin Bustam, Mohamad Azmi Suhaimi, Nadia Hartini
Copyright Year	2022
Description	$CO_{2}$ separation from raw natural gas can be achieved through the use of the promising membrane-based technology. Polymeric membranes are a known method for separating $CO_{2}$ but suffer from trade-offs between its permeability and selectivity. Therefore, through the use of mixed matrix membranes (MMMs) which utilizes inorganic or hybrid fillers such as metal-organic frameworks (MOFs) in polymeric matrix, the permeability and selectivity trade-off can be overcome and possibly surpass the Robeson Upper Bounds. In this study, various types of MOFs are explored in terms of its structure and properties such as thermal and chemical stability. Next, the use of amine and non-amine functionalized MOFs in MMMs development are compared in order to investigate the effects of amine functionalization on the membrane gas separation performance for flat sheet and hollow fiber configurations as reported in the literature. Moreover, the gas transport properties and various challenges faced by hollow fiber mixed matrix membranes (HFMMMs) are discussed. In addition, the utilization of amine functionalization MOF for mitigating the challenges faced is included. Finally, the future directions of amine-functionalized MOF HFMMMs are discussed for the fields of $CO_{2}$ separation.
Starting Page	1408
e-ISSN	20734360
DOI	10.3390/polym14071408
Journal	Polymers
Issue Number	7
Volume Number	14
Language	English
Publisher	MDPI
Publisher Date	2022-03-30
Access Restriction	Open
Subject Keyword	Polymers Environmental Engineering Metal-organic Frameworks (mofs) Amine-functionalized Mixed Matrix Hollow Fiber Membranes Co2/ch4 Separation
Content Type	Text
Resource Type	Article

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