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Facile Synthesis of N-Doped $WS_{2}$ Nanosheets as an Efficient and Stable Electrocatalyst for Hydrogen Evolution Reaction in Acidic Media
| Content Provider | MDPI |
|---|---|
| Author | Nayak, Arpan Kumar Enhtuwshin, Enhbayar Kim, So Jung Han, Hyuksu |
| Copyright Year | 2020 |
| Description | Transition metal chalcogenides have been widely studied as a promising electrocatalyst for the hydrogen evolution reaction (HER) in acidic conditions. Among various transition metal chalcogenides, tungsten disulfide (WS2) is a distinguishable candidate due to abundant active sites and good electrical properties. Herein, we report a facile and selective synthetic method to synthesize WS2 with an intriguing two-dimensional nanostructure by using cysteine (C3H7NO2S) as a chemical agent. In addition, nitrogen can be incorporated during chemical synthesis from cysteine, which may be helpful for enhancing the HER. The electrocatalytic activity of N-doped WS2 exhibits a promising HER in acidic conditions, which are not only higher than W18O49 nanowires and hex-WO3 nanowires, but also comparable to the benchmark Pt/C. Moreover, excellent electrocatalytic stability is also demonstrated for acidic HER during long-term tests, thus highlighting its potential use of practical applications as an electrolyzer. |
| Starting Page | 1238 |
| e-ISSN | 20734344 |
| DOI | 10.3390/catal10111238 |
| Journal | Catalysts |
| Issue Number | 11 |
| Volume Number | 10 |
| Language | English |
| Publisher | MDPI |
| Publisher Date | 2020-10-26 |
| Access Restriction | Open |
| Subject Keyword | Catalysts Inorganic Chemistry Water Splitting Hydrogen Evolution Reaction Electrocatalyst Tungsten Sulfide |
| Content Type | Text |
| Resource Type | Article |