NDLI: Fabrication and Characterization of Xanthan Gum-cl-poly(acrylamide-co-alginic acid) Hydrogel for Adsorption of Cadmium Ions from Aqueous Medium

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Fabrication and Characterization of Xanthan Gum-cl-poly(acrylamide-co-alginic acid) Hydrogel for Adsorption of Cadmium Ions from Aqueous Medium

Content Provider	MDPI
Author	Alberto, García-Peñas Sharma, Gaurav Kumar, Amit Ghfar, Ayman A. Naushad, Mu. Stadler, Florian J.
Copyright Year	2021
Description	The present research demonstrates the facile fabrication of xanthan gum-cl-poly(acrylamide-co-alginic acid) (XG-cl-poly(AAm-co-AA)) hydrogel by employing microwave-assisted copolymerization. Simultaneous copolymerization of acrylamide (AAm) and alginic acid (AA) onto xanthan gum (XG) was carried out. Different samples were fabricated by changing the concentrations of AAm and AA. A sample with maximum swelling percentage was chosen for adsorption experiments. The structural and functional characteristics of synthesized hydrogel were elucidated using diverse characterization tools. Adsorption performance of XG-cl-poly(AAm-co-AA) hydrogel was investigated for the removal of noxious cadmium (Cd(II)) ions using batch adsorption from the aqueous system, various reaction parameters optimized include pH, contact time, temperature, and concentration of Cd(II) ions and temperature. The maximum adsorption was achieved at optimal pH 7, contact time 180 min, temperature 35 °C and cadmium ion centration of 10 $mg·L^{−1}$. The XG-cl-poly(AAm-co-AA) hydrogel unveiled a very high adsorption potential, and its adsorption capacities considered based on the Langmuir isotherm for Cd(II) ions was 125 $mg·g^{−1}$ at 35 °C. The Cd(II) ions adsorption data fitted nicely to the Freundlich isotherm and pseudo-first-order model. The reusability investigation demonstrated that hydrogel retained its adsorption capacity even after several uses without significant loss.
Starting Page	23
e-ISSN	23102861
DOI	10.3390/gels8010023
Journal	Gels
Issue Number	1
Volume Number	8
Language	English
Publisher	MDPI
Publisher Date	2021-12-27
Access Restriction	Open
Subject Keyword	Gels Environmental Engineering Xanthum Gum Polyacrylamide Cadmium Ions Adsorption Langmuir Freundlich
Content Type	Text
Resource Type	Article

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