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New Mononuclear Mn(III) Complexes with Hydroxyl-Substituted Hexadentate Schiff Base Ligands
| Content Provider | MDPI |
|---|---|
| Author | Xu, Peng-Yu Wang, Yu-Ting Yu, Zong-Mei Li, Yong-Hua Wang, Shi |
| Copyright Year | 2021 |
| Description | This paper reports the syntheses, crystal structures and magnetic properties of Mn(III) hexadentate Schiff base complexes [Mn(4-OH-sal-N-1,5,8,12)]NO3(1) and [Mn(4-OH-sal-N-1,5,8,12)]ClO4(2), where (4-OH-sal-N-1,5,8,12)2− (4,4′-((1E,13E)-2,6,9,13-tetraazatetradeca-1,13-diene-1,14-diyl)bis(3-methoxyphenol) is a new hydroxyl-substituted hexadentate Schiff base ligand. The introduction of the (4-OH-sal-N-1,5,8,12)2− ligand induces more hydrogen bonding interactions, in addition to promoting the formation of intermolecular interactions among the cations. However, the close-packing structures of both complexes lead to their stabilization in the high-spin state in the temperature range of 2−300 K. |
| Starting Page | 12 |
| e-ISSN | 23127481 |
| DOI | 10.3390/magnetochemistry7010012 |
| Journal | Magnetochemistry |
| Issue Number | 1 |
| Volume Number | 7 |
| Language | English |
| Publisher | MDPI |
| Publisher Date | 2021-01-13 |
| Access Restriction | Open |
| Subject Keyword | Magnetochemistry Inorganic Chemistry Spin Crossover Manganese(iii) Hydrogen Bonding Crystal Structure |
| Content Type | Text |
| Resource Type | Article |
