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Titanium-Modified MIL-101(Cr) Derived Titanium-Chromium-Oxide as Highly Efficient Oxidative Desulfurization Catalyst
| Content Provider | MDPI |
|---|---|
| Author | Li, Xiaolin Zhang, Liang Sun, Yin Yong |
| Copyright Year | 2020 |
| Description | A titanium-chromium-oxide catalyst was prepared by a facile calcination of titanium-modified MIL-101(Cr). The resulting material, possessing a surface area of 60 m2 g−1 and a titania content of 50.0 wt%, can be directly used as the catalyst for oxidative desulfurization (ODS) reaction of dibenzothiophene (DBT). This novel ODS catalyst can remove 900 ppm sulfur-containing compounds in a reaction time of 30 min at 60 °C. The experimental results showed that the specific activity increased with the titanium content. The specific activity of the catalyst with 50%Ti reached 129 μmol/m2, which was much higher than that of reported Ti-based catalysts. |
| Starting Page | 1091 |
| e-ISSN | 20734344 |
| DOI | 10.3390/catal10091091 |
| Journal | Catalysts |
| Issue Number | 9 |
| Volume Number | 10 |
| Language | English |
| Publisher | MDPI |
| Publisher Date | 2020-09-20 |
| Access Restriction | Open |
| Subject Keyword | Catalysts Mil-101(cr), Anatase Titania Dbt Oxidative Desulfurization |
| Content Type | Text |
| Resource Type | Article |
