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Highly Efficient and Ambient-Temperature Synthesis of Benzimidazoles via Co(III)/Co(II)-Mediated Redox Catalysis
| Content Provider | MDPI |
|---|---|
| Author | Zhong, Renyuan Xiong, Wulin Zhang, Haoyuan Zeng, Tongtong Gong, Shanshan Sun, Qi |
| Copyright Year | 2022 |
| Description | An efficient method for ambient-temperature synthesis of a variety of 2-substituted and 1,2-disubstituted benzimidazoles from aldehyde and phenylenediamine substrates has been developed by utilizing Co(III)/Co(II)-mediated redox catalysis. The combination of only 1 mol% of $Co(acac)_{2}$ and stoichiometric amount of hydrogen peroxide provides a fast, green, and mild access to a diversity of benzimidazoles under solvent-free conditions. |
| Starting Page | 59 |
| e-ISSN | 20734344 |
| DOI | 10.3390/catal12010059 |
| Journal | Catalysts |
| Issue Number | 1 |
| Volume Number | 12 |
| Language | English |
| Publisher | MDPI |
| Publisher Date | 2022-01-05 |
| Access Restriction | Open |
| Subject Keyword | Catalysts Benzimidazole Co(acac)2 Redox Catalysis Oxidative Dehydrogenation Multivalent Transition Metal Catalyst |
| Content Type | Text |
| Resource Type | Article |