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Degradation Efficiency and Kinetics Analysis of an Advanced Oxidation Process Utilizing Ozone, Hydrogen Peroxide and Persulfate to Degrade the Dye Rhodamine B
| Content Provider | MDPI |
|---|---|
| Author | Zawadzki, Piotr Deska, Małgorzata |
| Copyright Year | 2021 |
| Description | In this study, the effectiveness of a rhodamine B (RhB) dye degradation process at a concentration of 20 mg/L in different advanced oxidation $processes—H_{2}O_{2}$/UV, $O_{3}$/UV and PDS/UV—has been studied. The use of UV in a photo-assisted ozonation process $(O_{3}$/UV) proved to be the most effective method of RhB decolorization (90% after 30 min at dye concentration of 100 mg/L). The addition of sulfate radical precursors (sodium persulfate, PDS) to the reaction environment did not give satisfactory effects (17% after 30 min), compared to the PDS/UV system (70% after 30 min). No rhodamine B decolorization was observed using hydrogen peroxide as a sole reagent, whereas an effect on the degree of RhB degradation was observed when UV rays strike the sample with $H_{2}O_{2}$ (33% after 30 min). The rhodamine B degradation process followed the pseudo-first-order kinetics model. The combined $PDS/O_{3}$/UV process has shown 60% color removal after 30 min of reaction time at an initial dye concentration of 100 mg/L. A similar effectiveness was obtained by only applying ozone or UV-activated persulfate, but at a concentration 2–5 times lower (20 mg/L). The results indicated that the combined $PDS/O_{3}$/UV process is a promising method for high RhB concentrations (50–100 mg/L) comparing to other alternative advanced oxidation processes. |
| Starting Page | 974 |
| e-ISSN | 20734344 |
| DOI | 10.3390/catal11080974 |
| Journal | Catalysts |
| Issue Number | 8 |
| Volume Number | 11 |
| Language | English |
| Publisher | MDPI |
| Publisher Date | 2021-08-14 |
| Access Restriction | Open |
| Subject Keyword | Catalysts Water Science and Technology Rhodamine B Dye Advanced Oxidation Process Radicals Kinetics |
| Content Type | Text |
| Resource Type | Article |