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Fluorescence Enhancement via Dual Coupling of Dye Molecules with Silver Nanostructures
| Content Provider | MDPI |
|---|---|
| Author | Tran, Vien Thi Ju, Heongkyu |
| Copyright Year | 2021 |
| Description | We demonstrate the enhancement of fluorescence emitted from dye molecules coupled with two surface plasmons, i.e., silver nanoparticles (AgNPs)-induced localized surface plasmons (LSP) and thin silver (Ag) film supported surface plasmons. Excitation light is illuminated to a $SiO_{2}$ layer that contains both rhodamine 110 molecules and AgNPs. AgNPs enhances excitation rates of dye molecules in their close proximity due to LSP-induced enhancement of local electromagnetic fields at dye excitation wavelengths. Moreover, the $SiO_{2}$ layer on one surface of which a 50 nm-thick Ag film is coated for metal cladding (air on the other surface), acts as a waveguide core at the dye emission wavelengths. The Ag film induces the surface plasmons which couple with the waveguide modes, resulting in a waveguide-modulated version of surface plasmon coupled emission (SPCE) for different $SiO_{2}$ thicknesses in a reverse Kretschmann configuration. We find that varying the $SiO_{2}$ thickness modulates the fluorescent signal of SPCE, its modulation behavior being in agreement with the theoretical simulation of thickness dependent properties of the coupled plasmon waveguide resonance. This enables optimization engineering of the waveguide structure for enhancement of fluorescent signals. The combination of LSP enhanced dye excitation and the waveguide-modulated version of SPCE may offer chances of enhancing fluorescent signals for a highly sensitive fluorescent assay of biomedical and chemical substances. |
| Starting Page | 217 |
| e-ISSN | 22279040 |
| DOI | 10.3390/chemosensors9080217 |
| Journal | Chemosensors |
| Issue Number | 8 |
| Volume Number | 9 |
| Language | English |
| Publisher | MDPI |
| Publisher Date | 2021-08-10 |
| Access Restriction | Open |
| Subject Keyword | Chemosensors Surface Plasmon Coupled Emission Waveguide Localized Surface Plasmon Fluorescence Enhancement Metal Nanostructures |
| Content Type | Text |
| Resource Type | Article |