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Observation of Distribution of π-Orbital-Oriented Domains in PAN- and Pitch-Based Carbon Fibers Using Scanning Transmission X-ray Microscopy
| Content Provider | MDPI |
|---|---|
| Author | Harano, Takayuki Takeichi, Yasuo Usui, Masafumi Arai, Yutaka Murao, Reiko Negi, Noriyuki Kimura, Masao |
| Copyright Year | 2020 |
| Description | The mechanical properties of carbon fibers (CFs) can be controlled by their internal structures such as the distribution of π-orbital-oriented domains, as well as the diameter and cross-sectional shape of the fiber. In this study, we investigated the carbon chemical structure maps of commercial polyacrylonitrile (PAN)- and pitch-based CFs using scanning transmission X-ray microscopy to evaluate the differences in the distribution of π-orbital-oriented domains. The graphene sheets in the PAN-based CFs have a fiber texture that is aligned along the fiber direction and randomly oriented within the cross section. The domain sizes within the cross section are less than the resolution limit (i.e., 50 nm). By contrast, the graphene sheets in the pitch-based CFs are aligned parallel to each other and form aggregates with a size ranging from approximately 100 nm to 1 μm within the cross sections. They form 200–300-nm stripes along the CF axis in the longitudinal sections. |
| Starting Page | 4836 |
| e-ISSN | 20763417 |
| DOI | 10.3390/app10144836 |
| Journal | Applied Sciences |
| Issue Number | 14 |
| Volume Number | 10 |
| Language | English |
| Publisher | MDPI |
| Publisher Date | 2020-07-14 |
| Access Restriction | Open |
| Subject Keyword | Applied Sciences Spectroscopy Carbon Fiber Polyacrylonitrile (pan) Pitch Orbital Orientation Scanning Transmission X-ray Microscopy (stxm) X-ray Absorption Near-edge Structure (xanes) |
| Content Type | Text |
| Resource Type | Article |