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Hybrid Materials Formed with Green Metal-Organic Frameworks and Polystyrene as Sorbents in Dispersive Micro-Solid-Phase Extraction for Determining Personal Care Products in Micellar Cosmetics
| Content Provider | MDPI |
|---|---|
| Author | Adri, án Gutiérrez-Serpa Ana, I. Jiménez-Abizanda Francisco, Jiménez-Moreno Jorge, Pasán Napolitano-Tabares, Patricia I. Pino, Verónica |
| Copyright Year | 2022 |
| Description | Hybrid materials based on polystyrene (PS) and green metal-organic frameworks (MOFs) were synthesized, characterized, and evaluated as potential sorbents in dispersive micro-solid-phase extraction (µ-dSPE). Among the resulting materials, the hybrid PS/DUT-67(Zr) was selected as the adequate extraction material for the monitoring of six personal care products in micellar cosmetic samples, combining the µ-dSPE method with ultra-high performance liquid chromatography (UHPLC) coupled to ultraviolet/visible detection (UV/Vis). Univariate studies and a factorial design were performed in the optimization of the microextraction procedure. The compromise optimum extraction conditions included 20 mg of PS/DUT-67(Zr) for 10 mL of sample, 2 min of extraction time, and two desorption steps using 100 µL of acetonitrile and 5 min assisted by vortex in each one. The validated μ-dSPE-UHPLC-UV/Vis method presented limits of detection and quantification down to 3.00 and 10.0 $μg·L^{−1}$, respectively. The inter-day precision values were lower than 23.5 and 21.2% for concentration levels of 75 $μg·L^{−1}$ and 650 $μg·L^{−1}$, respectively. The hydrophobicity of the resulting PS/DUT-67(Zr) material was crucial for the improvement of its extraction capacity in comparison with its unitary components, showing the advantages of combining MOFs with other materials, getting new sorbents with interesting properties. |
| Starting Page | 813 |
| e-ISSN | 14203049 |
| DOI | 10.3390/molecules27030813 |
| Journal | Molecules |
| Issue Number | 3 |
| Volume Number | 27 |
| Language | English |
| Publisher | MDPI |
| Publisher Date | 2022-01-26 |
| Access Restriction | Open |
| Subject Keyword | Molecules Analytical Chemistry Metal-organic Frameworks Polystyrene Polymeric Hybrid Materials Dispersive Micro-solid-phase Extraction Personal Care Products |
| Content Type | Text |
| Resource Type | Article |
