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Nanostructure Sn/C Composite High-Performance Negative Electrode for Lithium Storage
| Content Provider | MDPI |
|---|---|
| Author | Saddique, Jaffer Shen, Honglie Ge, Jiawei Huo, Xiaomin Rahman, Nasir Ahmadi, Ahmad Aziz Al Mushtaq, Muhammad |
| Copyright Year | 2022 |
| Description | Tin-based nanocomposite materials embedded in carbon frameworks can be used as effective negative electrode materials for lithium-ion batteries (LIBs), owing to their high theoretical capacities with stable cycle performance. In this work, a low-cost and productive facile hydrothermal method was employed for the preparation of a Sn/C nanocomposite, in which Sn particles (sized in nanometers) were uniformly dispersed in the conductive carbon matrix. The as-prepared Sn/C nanocomposite displayed a considerable reversible capacity of 877 $mAhg^{−1}$ at 0.1 $Ag^{−1}$ with a high first cycle charge/discharge coulombic efficiency of about 77%, and showed 668 mAh/g even at a relatively high current density of 0.5 $Ag^{−1}$ after 100 cycles. Furthermore, excellent rate capability performance was achieved for 806, 697, 630, 516, and 354 $mAhg^{−1}$ at current densities 0.1, 0.25, 0.5, 0.75, and 1 $Ag^{−1}$, respectively. This outstanding and significantly improved electrochemical performance is attributed to the good distribution of Sn nanoparticles in the carbon framework, which helped to produce Sn/C nanocomposite next-generation negative electrodes for lithium-ion storage. |
| Starting Page | 4083 |
| e-ISSN | 14203049 |
| DOI | 10.3390/molecules27134083 |
| Journal | Molecules |
| Issue Number | 13 |
| Volume Number | 27 |
| Language | English |
| Publisher | MDPI |
| Publisher Date | 2022-06-24 |
| Access Restriction | Open |
| Subject Keyword | Molecules Sn-based Anode Material Synthesis Structural Characterization Lithium-ion Battery (lib) Electrochemical Performance |
| Content Type | Text |
| Resource Type | Article |