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Supramolecular Diiodine-Bromostannate(IV) Complexes: Narrow Bandgap Semiconductors
| Content Provider | MDPI |
|---|---|
| Author | Korobeynikov, Nikita A. Usoltsev, Andrey N. Abramov, Pavel A. Sokolov, Maxim N. Adonin, Sergey A. |
| Copyright Year | 2022 |
| Description | Three supramolecular bromostannates(IV) with “trapped” diiodine molecules, $Cat_{2}{[SnBr_{6}](I_{2}$)} (Cat = Me_{4}$N^{+}$ (1), $1-MePy^{+}$ (2) and 4-MePyH (3)), were synthesized. In all cases, $I_{2}$ linkers are connected with bromide ligands via halogen···halogen non-covalent interactions. Articles 1–3 were studied using Raman spectroscopy, thermogravimetric analysis, and diffuse reflectance spectroscopy. The latter indicates that 1–3 are narrow band gap semiconductors. |
| Starting Page | 3859 |
| e-ISSN | 14203049 |
| DOI | 10.3390/molecules27123859 |
| Journal | Molecules |
| Issue Number | 12 |
| Volume Number | 27 |
| Language | English |
| Publisher | MDPI |
| Publisher Date | 2022-06-16 |
| Access Restriction | Open |
| Subject Keyword | Molecules Polyhalogens Halogen Bonding Non-covalent Interactions Tin Halide Complexes Iodine |
| Content Type | Text |
| Resource Type | Article |
