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Synthesis and Reactivity of Manganese Complexes Bearing Anionic PNP- and PCP-Type Pincer Ligands toward Nitrogen Fixation
| Content Provider | MDPI |
|---|---|
| Author | Kuriyama, Shogo Wei, Shenglan Kato, Takeru Nishibayashi, Yoshiaki |
| Copyright Year | 2022 |
| Description | A series of manganese complexes bearing an anionic pyrrole-based PNP-type pincer ligand and an anionic benzene-based PCP-type pincer ligand is synthesized and characterized. The reactivity of these complexes toward ammonia formation and silylamine formation from dinitrogen under mild conditions is evaluated to produce only stoichiometric amounts of ammonia and silylamine, probably because the manganese pincer complexes are unstable under reducing conditions. |
| Starting Page | 2373 |
| e-ISSN | 14203049 |
| DOI | 10.3390/molecules27072373 |
| Journal | Molecules |
| Issue Number | 7 |
| Volume Number | 27 |
| Language | English |
| Publisher | MDPI |
| Publisher Date | 2022-04-06 |
| Access Restriction | Open |
| Subject Keyword | Molecules Manganese Nitrogen Fixation Pincer Ligand |
| Content Type | Text |
| Resource Type | Article |
