NDLI: Filler Effects on $H_{2}$ Diffusion Behavior in Nitrile Butadiene Rubber Blended with Carbon Black and Silica Fillers of Different Concentrations

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Filler Effects on $H_{2}$ Diffusion Behavior in Nitrile Butadiene Rubber Blended with Carbon Black and Silica Fillers of Different Concentrations

Content Provider	MDPI
Author	Jung, Jae Kap Lee, Chang Hoon Son, Min Seok Lee, Ji Hun Baek, Un Bong Chung, Ki Soo Choi, Myung Chan Bae, Jong Woo
Copyright Year	2022
Description	Filler effects on $H_{2}$ diffusion in nitrile butadiene rubbers (NBRs) blended with carbon black and silica fillers of different concentrations are first investigated by employing a volumetric analysis. Total uptake, solubility, and diffusivity of hydrogen for ten filled-NBR, including neat NBR, are determined in an exposed pressure range of 1.3 MPa~92.6 MPa. Filler dependence on hydrogen uptake and diffusion is distinctly observed in the NBRs blended with high abrasion furnace (HAF) carbon black (CB) fillers compared to NBRs blended with medium thermal furnace (MT) CB and silica filler, which is related to the specific surface area of carbon black and interface structure. The HAF CB filled-NBR follows dual sorption behavior combined with Henry’s law and the Langmuir model, responsible for two contributions of solubility from polymer and filler. However, a single gas sorption behavior coming from the polymer is observed satisfying Henry’s law up to 92.6 MPa for NBR blended with MT CB filled-NBR and silica filled-NBR. Diffusion demonstrates Knudsen and bulk diffusion behavior below and above, respectively, at certain pressures. With increasing pressure, the filler effect on diffusion is reduced, and diffusivity converges to a value. The correlation observed between diffusivity and filler content (or crosslink density) is discussed.
Starting Page	700
e-ISSN	20734360
DOI	10.3390/polym14040700
Journal	Polymers
Issue Number	4
Volume Number	14
Language	English
Publisher	MDPI
Publisher Date	2022-02-11
Access Restriction	Open
Subject Keyword	Polymers Environmental Engineering Nitrile Butadiene Rubber (nbr) Carbon Black Filler Silica Filler Volumetric Analysis Hydrogen Uptake Diffusion Permeability
Content Type	Text
Resource Type	Article

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