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Synthesis and Characterization of New Guanine Complexes of Pt(IV) and Pd(II) by X-ray Diffraction and Hirshfeld Surface Analysis
| Content Provider | MDPI |
|---|---|
| Author | Novikov, Anton Petrovich Volkov, Mikhail Alexandrovich Safonov, Alexey Vladimirovich Grigoriev, Mikhail Semenovich Abkhalimov, Evgeny Vladilenovich |
| Copyright Year | 2021 |
| Description | The aim of the work was to synthesize new perspective compounds of palladium and platinum with nitrogenous bases (guanine), promising for use in biomedicine and catalysis. The article describes the synthesis of new $[PdCl_{2}(HGua)_{2}]Cl_{2}·H_{2}$O and $[PtCl_{5}(HGua)]·2H_{2}$O compounds using wet chemistry methods. The structure of the obtained single crystals was established by the method of single crystal X-ray diffraction. The complexes have an M-N bond, and the organic ligand is included in the first coordination sphere. The analysis of Hirshfeld surfaces for the obtained complexes and their analogues for the analysis of intermolecular interactions was carried out. In the palladium complex we obtained, π-halogen and π-stacking interactions were found; in analogues, such interactions were not found. π-halogen and halogen interactions were found in structure of platinum complex and its analogues. |
| Starting Page | 1417 |
| e-ISSN | 20734352 |
| DOI | 10.3390/cryst11111417 |
| Journal | Crystals |
| Issue Number | 11 |
| Volume Number | 11 |
| Language | English |
| Publisher | MDPI |
| Publisher Date | 2021-11-19 |
| Access Restriction | Open |
| Subject Keyword | Crystals X-ray Diffraction Analysis Hirshfeld Surface Analysis Guanine Palladium Platinum Metal-nitrogen Bond |
| Content Type | Text |
| Resource Type | Article |
