NDLI: Lanthanoid-Anilato Complexes and Lattices

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Lanthanoid-Anilato Complexes and Lattices

Content Provider	MDPI
Author	Carlos, J. Gómez-García Benmansour, Samia
Copyright Year	2020
Description	In this review, we describe all the structurally characterized complexes containing lanthanoids (Ln, including La and group 3 metals: Y and Lu) and any anilato-type ligand (3,6-disubstituted-2,5-dihydroxy-1,4-benzoquinone dianion = C6O4X22−). We present all the anilato-Ln compounds including those where, besides the anilato-type ligand, there is one or more coligands or solvent molecules coordinated to the lanthanoid ions. We show the different structural types observed in these compounds: from discrete monomers, dimers and tetramers to extended 1D, 2D and 3D lattices with different topologies. We also revise the magnetic properties of these Ln-anilato compounds, including single-molecule magnet (SMM) and single-ion magnet (SIM) behaviours. Finally, we show the luminescent and electrochemical properties of some of them, their gas/solvent adsorption/absorption and exchange capacity and the attempts to prepare them as thin films.
Starting Page	71
e-ISSN	23127481
DOI	10.3390/magnetochemistry6040071
Journal	Magnetochemistry
Issue Number	4
Volume Number	6
Language	English
Publisher	MDPI
Publisher Date	2020-12-15
Access Restriction	Open
Subject Keyword	Magnetochemistry Inorganic Chemistry Lanthanoid Anilato X-ray Structure Magnetic Properties Luminescence Single-ion Magnet Single-molecule Magnet Solvent Exchange
Content Type	Text
Resource Type	Article

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