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New Trends in the Conversion of $CO_{2}$ to Cyclic Carbonates
| Content Provider | MDPI |
|---|---|
| Author | Lopes, Erivaldo Ribeiro, Ana Martins, Luísa |
| Copyright Year | 2020 |
| Description | This work concerns recent advances (mainly in the last five years) in the challenging conversion of carbon dioxide $(CO_{2}$) into fine chemicals, in particular to cyclic carbonates, as a meaningful measure to reduce $CO_{2}$ emissions in the atmosphere and subsequent global warming effects. Thus, efficient catalysts and catalytic processes developed to convert $CO_{2}$ into different chemicals towards a more sustainable chemical industry are addressed. Cyclic carbonates can be produced by different routes that directly, or indirectly, use carbon dioxide. Thus, recent findings on $CO_{2}$ cycloaddition to epoxides as well as on its reaction with diols are reviewed. In addition, indirect sources of carbon dioxide, such as urea, considered a sustainable process with high atom economy, are also discussed. Reaction mechanisms for the transformations involved are also presented. |
| Starting Page | 479 |
| e-ISSN | 20734344 |
| DOI | 10.3390/catal10050479 |
| Journal | Catalysts |
| Issue Number | 5 |
| Volume Number | 10 |
| Language | English |
| Publisher | MDPI |
| Publisher Date | 2020-04-27 |
| Access Restriction | Open |
| Subject Keyword | Catalysts Organic Chemistry Carbon Dioxide Cyclic Carbonate Diol Epoxide Catalysis Co2 Conversion |
| Content Type | Text |
| Resource Type | Article |