NDLI: On the Morphology of the SDS Film on the Surface of Borosilicate Glass

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On the Morphology of the SDS Film on the Surface of Borosilicate Glass

Content Provider	MDPI
Author	Shen, Zih-Yao Lee, Maw-Tien
Abstract	Surfactant films on solid surfaces have attracted much attention because of their scientific interest and applications, such as surface treatment agent, or for micro- or nano-scale templates for microfluidic devices. In this study, anionic surfactant sodium dodecyl sulfate (SDS) solutions with various charged inorganic salts was spread on a glass substrate and dried to form an SDS thin film. Atomic force microscopy (AFM) was employed to observe the micro-structure of the SDS thin film. The effects of inorganic salts on the morphology of the SDS film were observed and discussed. The results of experiments demonstrated that pure SDS film formed patterns of long, parallel, highly-ordered stripes. The existence of the inorganic salt disturbed the structure of the SDS film due to the interaction between the cationic ion and the anionic head groups of SDS. The divalent ion has greater electrostatic interaction with anionic head groups than that of the monovalent ion, and causes a gross change in the morphology of the SDS film. The height of the SDS bilayer measured was consistent with the theoretical value, and the addition of the large-sized monovalent ion would lead to lowering the height of the adsorbed structures.
File Size	9098240
File Format	PDF
e-ISSN	19961944
DOI	10.3390/ma10050555
Journal	Materials
Issue Number	5
Volume Number	10
Language	English
Publisher Date	2017-05-19
Access Restriction	Open
Subject Keyword	surfactant adsorption film atomic force microscopy sodium dodecyl sulfate
Content Type	Text
Resource Type	Article

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