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  1. Energies
  2. Volume: 3
  3. Issue: 11
  4. Catalytic Upgrading of Biomass Fast Pyrolysis Vapors with Nano Metal Oxides: An Analytical Py-GC/MS Study
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Volume: 11
Volume: 10
Volume: 9
Volume: 8
Volume: 7
Volume: 6
Volume: 5
Volume: 4
Volume: 3
Issue: 12
Issue: 11
Dynamic Modeling and Simulation on a Hybrid Power System for Electric Vehicle Applications
Catalytic Upgrading of Biomass Fast Pyrolysis Vapors with Nano Metal Oxides: An Analytical Py-GC/MS Study
Scale Effects on Quasi-Steady Solid Rocket Internal Ballistic Behaviour
A Review of Fusion and Tokamak Research Towards Steady-State Operation: A JAEA Contribution
Electrostatic Discharge Current Linear Approach and Circuit Design Method
A Photovoltaic Device Using an Electrolyte Containing Photosynthetic Reaction Centers
Performance Analysis of a Double-effect Adsorption Refrigeration Cycle with a Silica Gel/Water Working Pair
Issue: 10
Issue: 9
Issue: 8
Issue: 7
Issue: 6
Issue: 5
Issue: 4
Issue: 3
Issue: 2
Issue: 1
Volume: 2
Volume: 1

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Catalytic Upgrading of Biomass Fast Pyrolysis Vapors with Nano Metal Oxides: An Analytical Py-GC/MS Study

Content Provider MDPI
Author Lu, Qiang Zhang, Zhi-Fei Dong, Chang-Qing Zhu, Xi-Feng
Abstract Fast pyrolysis of poplar wood followed with catalytic cracking of the pyrolysis vapors was performed using analytical pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS). The catalysts applied in this study were nano MgO, CaO, TiO2, Fe2O3, NiO and ZnO. These catalysts displayed different catalytic capabilities towards the pyrolytic products. The catalysis by CaO significantly reduced the levels of phenols and anhydrosugars, and eliminated the acids, while it increased the formation of cyclopentanones, hydrocarbons and several light compounds. ZnO was a mild catalyst, as it only slightly altered the pyrolytic products. The other four catalysts all decreased the linear aldehydes dramatically, while the increased the ketones and cyclopentanones. They also reduced the anhydrosugars, except for NiO. Moreover, the catalysis by Fe2O3 resulted in the formation of various hydrocarbons. However, none of these catalysts except CaO were able to greatly reduce the acids.
File Size 306176
Ending Page 1820
Page Count 16
Starting Page 1805
File Format PDF
e-ISSN 19961073
DOI 10.3390/en3111805
Journal Energies
Issue Number 11
Volume Number 3
Language English
Publisher Date 2010-11-15
Access Restriction Open
Subject Keyword biomass fast pyrolysis catalytic cracking Py-GC/MS nano metal oxides
Content Type Text
Resource Type Article
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