NDLI: Chiral Discrimination Of Secondary Alcohols And Carboxylic Acids By NMR Spectroscopy

Content Provider	Indian Institute of Science (IISc)
Author	Pal, Indrani Chaudhari, Sachin R. Suryaprakash, Nagaraja Rao
Copyright Year	2015
Abstract	The manuscript reports two novel ternary ion-pair complexes, which serve as chiral solvating agents, for enantiodiscrimination of secondary alcohols and carboxylic acids. The protocol for discrimination of secondary alcohols is designed by using one equivalent mixture each of enantiopure mandelic acid, 4-dimethylaminopyridine (DMAP) and a chiral alcohol. For discrimination of carboxylic acids, the ternary complex is obtained by one equivalent mixture each of enantiopure chiral alcohol, DMAP and a carboxylic acid. The designed protocols also permit accurate measurement of enantiomeric composition. Copyright (C) 2014 John Wiley & Sons, Ltd.
File Format	PDF
Journal	NonPeerReviewed
Language	English
Publisher	WILEY-BLACKWELL
Publisher Date	2015-01-01
Access Restriction	Authorized
Subject Keyword	Solid State & Structural Chemistry Unit
Content Type	Text
Resource Type	Article

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