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Preparation And Characterization Of Hydrazine Derivatives. Part-II: Reaction Of Transition Metal Ammonium Double Sulphates With Hydrazine Hydrate
| Content Provider | Indian Institute of Science (IISc) |
|---|---|
| Author | Patil, K. C. Soundararajan, R. Verneker, Pai Vr |
| Copyright Year | 1979 |
| Abstract | Transition metal ammonium double sulphates (NH4)2M(SO4)2¨ 6H2O, where M = Fe, Co and Ni react with hydrazine hydrate in air giving crystalline compounds of the general formula (N2H5) [M(N2H3COO)3] H2O. The reaction proceeds through (N2H5)2 M(SO4)2, ¨ 3N2H4, (N2H5)2 [M(OH)4 ¨ (N2H4)2], M(N2H3COO)2 ¨ (N2H4)2 and N2H5 [M(N2 H3 COO)3] intermediates. The reaction sequence is followed by chemical analysis and infrared spectra. A possible reaction mechanism has been suggested. |
| File Format | |
| Journal | PeerReviewed |
| Language | English |
| Publisher | Indian Academy of Sciences |
| Publisher Date | 1979-01-01 |
| Access Restriction | Authorized |
| Subject Keyword | Inorganic & Physical Chemistry Others |
| Content Type | Text |
| Resource Type | Article |
