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Construction Of Vicinal Quaternary Carbon Atoms By Ireland Ester Claisen Rearrangement: Total Synthesis Of $(\pm)$-herbertenolide, $(\pm)$-herberteneacetal, $(\pm)$-herbertene-1,14-diol And $(\pm)$-herbertene-1,15-diol
| Content Provider | Indian Institute of Science (IISc) |
|---|---|
| Author | Srikrishna, A. Lakshmi, Vasantha B. |
| Copyright Year | 2005 |
| Abstract | Efficient total syntheses of the herbertane sesquiterpene title compounds have been accomplished employing an Ireland ester Claisen rearrangement and ring-closing metathesis reaction sequence based strategy for the construction of two stereogenic vicinal quaternary carbon atoms on a cyclopentane. (c) 2005 Elsevier Ltd. All rights reserved. |
| File Format | |
| Journal | PeerReviewed |
| Language | English |
| Publisher | Elsevier |
| Publisher Date | 2005-07-18 |
| Access Restriction | Authorized |
| Subject Keyword | Organic Chemistry |
| Content Type | Text |
| Resource Type | Article |