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Oxidation Of Spiroalcohols With 2,3-Dichloro-5,6-Dicyano-1,4-Benzoquinone (Ddq) .4. Structure Of A Novel Dioxepin Derivative
| Content Provider | Indian Institute of Science (IISc) |
|---|---|
| Author | Jayaraman, K. S. Kasturi, T. R. |
| Copyright Year | 1991 |
| Abstract | DDQ oxidation of the spiroalcohol 7a gives exclusively a compound to which the 13a-methyl-13aH-7a, 15-methano-15H-dinaphtho[2,1-b:2',1'-e][1,4]-dioxepin structure 8a has been assigned on the basis of two-dimensional homonuclear (H-1-H-1) and heteronuclear (H-1-C-13; FUCOUP) correlation spectroscopy experiments. Similar oxidation of spiroalcohols 7b-h gives the dioxepin derivatives 8b-h. |
| File Format | |
| Journal | PeerReviewed |
| Language | English |
| Publisher | National Institute of Science Communication and Information Resources |
| Publisher Date | 1991-06-01 |
| Access Restriction | Authorized |
| Subject Keyword | Organic Chemistry |
| Content Type | Text |
| Resource Type | Article |
