NDLI: Diastereoisomeric ((Sj(B6-arene)ruthenium(II) Chiral Schiff Base Complexes: Crystal Structure Of A Triphenylphosphine Adduct

Content Provider	Indian Institute of Science (IISc)
Author	Mandal, Sisir K. Chakravarty, Akhil R.
Copyright Year	1991
Abstract	Reaction of [(eta-6-p-cymene)RuCl(L star)] with AgClO4 in Me2CO gives a perchlorate complex which on subsequent treatment with PPh3, gamma-picoline or Cl- yields adducts showing that there can be retention as well as inversion of configuration at the metal centre. The (R)Ru,(S)C absolute configurations of the chiral centres in the triphenylphosphine adduct have been established by an X-ray diffraction study [HL star, (S)-alpha-methylbenzylsalicylaldimine]. The CD spectral study reveals that there is an inversion of configuration during formation of the PPh3 adduct.
File Format	PDF
Journal	PeerReviewed
Language	English
Publisher	Elsevier science
Publisher Date	1991-10-08
Access Restriction	Authorized
Subject Keyword	Inorganic & Physical Chemistry
Content Type	Text

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