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Mixed Ligand Complexes In Vinyl Polymerization-II: [NN-ethylenebis(salicylideneiminato)] (benzoylacetonato)cobalt(III) As An Initiator
| Content Provider | Indian Institute of Science (IISc) |
|---|---|
| Author | Thiagarajan, R. Nandi, U. S. Kalpagam, V. |
| Copyright Year | 1982 |
| Abstract | The polymerization of methyl methacrylate initiated by a mixed ligand complex. [NN-ethylenebis(salicylideneiminato)](benzoylacetonato)cobalt(III) has been studied in bulk and in benzene at 70ãAÀ and 80ãAÀ. The rate of polymerization is proportional to (concentration of the chelate)Image and the monomer exponent is close to 1.5. The activation energy and the kinetic and transfer constants are evaluated. A free radical mechanism has been proposed. |
| File Format | |
| Journal | PeerReviewed |
| Language | English |
| Publisher | Elsevier Science |
| Publisher Date | 1982-01-01 |
| Access Restriction | Authorized |
| Subject Keyword | Inorganic & Physical Chemistry |
| Content Type | Text |
| Resource Type | Article |