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NMR Spectroscopic And X-Ray Structural Studies Of Two Diazadiphosphetidines
| Content Provider | Indian Institute of Science (IISc) |
|---|---|
| Author | Kumaravel, S. S. Rao, Sudhakara S. P. Krishnamurthy, S. S. Vincent, B. N. Cameron, T. S. |
| Copyright Year | 1987 |
| Abstract | The crystal structures of the two diazadiphosphetidines, [PhNP(OCH2CF3)]2 (1) and [MeNP(NMe2)(O2C6H4)]2 (2) have been determined. The trifluoroethoxy groups in (1) have a trans orientation. The phosphorus chemical shift for (1) is at 189.8 (Se(B. On standing in solution, (1) transforms slowly (∼ 10 days) and almost completely into its 'high-field' (cis) isomer (142.2(Se(B). |
| File Format | |
| Journal | PeerReviewed |
| Language | English |
| Publisher | Taylor and Francis Group |
| Publisher Date | 1987-04-01 |
| Access Restriction | Authorized |
| Subject Keyword | Inorganic & Physical Chemistry |
| Content Type | Text |
| Resource Type | Article |