NDLI: Supramolecular Organization In Tetra Aqua (mu-8-Hydroxyquinoline-5-sulfonate) Barium (II) And Ag Center Dot Center Dot Center Dot I Interactions In A Pseudopolymorphic Form Of (7-Iodo-8-hydroxyquinoline-5-sulfonate) Silver (I) Monohydrate

Content Provider	Indian Institute of Science (IISc)
Author	Balasubramani, K. Hemamalini, M. Francis, S. Muthiah, P. Thomas Vijay, T. Row, Tn Guru Bocelli, G. Cantoni, A.
Copyright Year	2010
Abstract	The complexes, Ba (HQS) (H2O)(4) (HQS = 8-hydroxyquinoline-5-sulfonic acid) (1) and Ag (HIQS) (H2O) (Ferron = 7-iodo-8-hydroxyquinoline-5-sulfonic acid) (2) have been synthesized and characterized by X-ray diffraction analysis and spectroscopic studies. In compound 1, Ba2+ ion has a nine-coordinate monocapped antiprismatic geometry. In compound 2, Ag+ has distorted tetrahedral coordination and Ag center dot center dot center dot I interactions generate the supramolecular architectures. The complexes have been characterized by FT-IR and UV-Visible measurements. In both the structures, the inversion-related organic ligands are stacked over one another leading to three-dimensional networks.
File Format	PDF
Journal	PeerReviewed
Language	English
Publisher	Springer
Publisher Date	2010-04-01
Access Restriction	Authorized
Subject Keyword	Solid State & Structural Chemistry Unit
Content Type	Text
Resource Type	Article

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