NDLI: E-Z Isomerization In Ethyl Cyano(hydrazono)acetate, A Push-pull Imine

Content Provider	Indian Institute of Science (IISc)
Author	Devendra, K. S. Balasubrahmanyam, S. N. Prasad, N.
Copyright Year	1990
Abstract	Transformation of the E form of Et cyanoglyoxalate phenylhydrazone (E-I) into Z-I is catalyzed by proton-acceptor-type H-bonding solvents (H-bonding bases). Kinetic and allied data gathered on the approach of E-I towards equil. with Z-I in acetone have been utilized to delimit possible processes by which acetone may catalyze the transformation, under the basic premise that a consequence of H-bonding by the base solvent is enhancement of electron d. at amino N.
File Format	PDF
Journal	PeerReviewed
Language	English
Publisher	National Institute of Science Communication and Information Resources
Publisher Date	1990-01-01
Access Restriction	Authorized
Subject Keyword	Organic Chemistry
Content Type	Text
Resource Type	Article

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