Loading...
Please wait, while we are loading the content...
Similar Documents
Halogen Exchange Reactions Of Silicon Tetrafluoride With Phosphorus Trichloride And Phosphoryl Chloride
| Content Provider | Indian Institute of Science (IISc) |
|---|---|
| Author | Suresh, B. S. Padma, D. K. |
| Copyright Year | 1985 |
| Abstract | Silicon tetrafluoride undergoes halogen exchange reactions with both phosphorus trichloride and phosphoryl chloride at temperatures of $500-600^0C$ yielding mixed chlorofluorides of silicon and phosphorus. It is interesting to note that,at these high temperatures, $PCl_3$ undergoes complete exchange to form $PF_3$ while $POCl_3$ reacts only with partial substitution, the major products being phosphorus chloride difluoride and silicon trichloride fluoride. |
| File Format | |
| Journal | PeerReviewed |
| Language | English |
| Publisher | Elsevier |
| Publisher Date | 1985-09-01 |
| Access Restriction | Authorized |
| Subject Keyword | Inorganic & Physical Chemistry |
| Content Type | Text |
| Resource Type | Article |
