NDLI: A New Method For The Preparation Of Sulphuryl Chloro Fluoride

Content Provider	Indian Institute of Science (IISc)
Author	Padma, D. K. Bhat, Subrahmanya V. Vasudevamurthy, A. R.
Copyright Year	1978
Abstract	It has been observed that a suspension of sodium fluoride in boiling acetonitrile could be used for the preparation of fluorine compounds such as silicon tetrafluoride [1], thiophosphoryl fluoride [2], sulphur tetrafluoride [3,4], and fluorocyclophosphazenes [5]. This method, when adopted for the fluorination of sulphuryl chloride [6], it is observed that a mixture of sulphuryl fluoride and sulphuryl chloro fluoride is obtained. On the other hand, when lead fluoride is substituted for sodium fluoride, pure sulphuryl chloro fluoride is evolved. Based on this observation, a new method has been standardised for the preparation of a pure sample of sulphuryl chlorofluoride by fluorinating sulphuryl chloride by lead fluoride in acetonitrile medium.
File Format	PDF
Journal	PeerReviewed
Language	English
Publisher	Elsevier Science
Publisher Date	1978-01-01
Access Restriction	Authorized
Subject Keyword	Inorganic & Physical Chemistry
Content Type	Text
Resource Type	Article

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