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| Content Provider | IET Digital Library |
|---|---|
| Author | Muralisankar, Indiran Agilan, Santhanam Selvakumar, Rajendran Vairam, Sundararajan |
| Abstract | This study discusses the use of Co3O4 impregnated graphene (CoOIG) as an efficient adsorbent for the removal of methyl violet (MV) dye from wastewater. CoOIG nanocomposites have been prepared by pyrolyzing paraffin wax with cobalt acetate. The synthesised nanocomposite was characterised by X-ray diffraction, field emission scanning electron microscope, transmission electron microscope, Fourier transform infrared spectroscope, Raman spectroscopy, and Brunauer–Emmett–Teller isotherm studies. The above studies indicate that the composites have cobalt oxide nanoparticles of size 51–58 nm embedded in the graphene nanoparticles. The adsorption studies were conducted with various parameters, pH, temperature and initial dye concentration, adsorbent dosage and contact time by the batch method. The adsorption of MV dye by the adsorbent CoOIG was about 90% initially at 15 min and 98% dye removal at pH 5. The data were fitted in Langmuir, Freundlich, Temkin, and Dubinin–Radushkevich and Sips isotherm models. Various thermodynamic parameters like Gibbs free energy, enthalpy, and entropy of the on-going adsorption process have also been calculated. |
| Starting Page | 787 |
| Ending Page | 794 |
| Page Count | 8 |
| ISSN | 17518741 |
| Volume Number | 12 |
| e-ISSN | 1751875X |
| Issue Number | Issue 6, Sep (2018) |
| Alternate Webpage(s) | https://digital-library.theiet.org/content/journals/iet-nbt/12/6 |
| Alternate Webpage(s) | https://digital-library.theiet.org/content/journals/10.1049/iet-nbt.2017.0181 |
| Journal | IET Nanobiotechnology |
| Publisher Date | 2018-03-23 |
| Access Restriction | Open |
| Rights Holder | © The Institution of Engineering and Technology |
| Subject Keyword | Adsorption Adsorption And Desorption Kinetics Brunauer-Emmett-Teller Isotherm Co3O4-C Cobalt Compounds Cobalt Oxide Nanoparticles Dyes Enthalpy Entropy Evaporation And Condensation Field Emission Electron Microscopy Field Emission Scanning Electron Microscopy Fourier Transform Infrared Spectra Fourier Transform Infrared Spectroscopy Free Energy Gibbs Free Energy Graphene Graphene NanoParticle Infrared And Raman Spectra in Inorganic Crystal Methyl Violet Dye Nanocomposite Nanofabrication Nanoparticle Nanotube And Nanostructured Material Paraffin Wax Raman Spectra Raman Spectroscopy Scanning Electron Microscopy Sorption And Accommodation Coefficient Structure of Solid Clusters Surface Chemistry Thermodynamic Parameter Thermodynamic Property And Entropy Transmission Electron Microscopy Water X-Ray Diffraction |
| Content Type | Text |
| Resource Type | Article |
| Subject | Nanoscience and Nanotechnology Electronic, Optical and Magnetic Materials Electrical and Electronic Engineering Biotechnology |
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