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| Content Provider | IEEE Xplore Digital Library |
|---|---|
| Author | Saeteaw, K. Tumcharern, G. Piyakulawat, P. Asawapirom, U. Porntheeraphat, S. Duangkaew, P. Maolanon, R. Piyananjaratsri, R. Nukeaw, J. Pratontep, S. |
| Copyright Year | 2011 |
| Description | Author affiliation: Thai Microelectronics Center (TMEC), National Electronics and Computer Technology Center (NECTEC), Chachoensao 24000, Thailand (Porntheeraphat, S.; Piyananjaratsri, R.) || College of Nanotechnology, King Mongkut's Institute of Technology Ladkrabang, Chalongkrung Rd., Bangkok 10520, Thailand (Saeteaw, K.; Nukeaw, J.; Pratontep, S.) || National Nanotechnology Center (NANOTEC), National Science and Technology Development Agency, Thailand Science Park, Patumtani 12120, Thailand (Tumcharern, G.; Piyakulawat, P.; Asawapirom, U.; Duangkaew, P.; Maolanon, R.) |
| Abstract | Rapid monitoring methods of heavy metals in water are in great demand for industrial environmental managements. This work aims to develop a heavy metal sensing device based on an electrochemical electronic tongue using a hybrid composite of metal oxide nanoparticles and conductive polymer as the working electrodes. The electrodes were prepared by drop-casting colloidal mixtures of Regioregular poly(3-hexylthiophene) (P3HT) and metal oxide nanoparticles (ZnO or TiO2) in chloroform onto a fluorine-doped tin oxide (FTO) glass. Optical microscopy measurements reveal some microstructural organization of the metal oxide-P3HT composite films on the electrodes, in comparison to a smooth P3HT film. Cyclic voltammetry (CV) measurements using bare FTO, P3HT, P3HT/ZnO and P3HT/TiO2 electrodes were performed on aqueous solutions of various metal acetates at the concentration of 0.01M. The Principal Component Analysis (PCA) was applied to the CV results to obtain the classification of the data from the various metal salt solutions. The PCA score plot exhibits a clear separation of the data groups of different heavy metals, with the highest distinction between zinc and lead. The PCA loading plot confirms that the different electrochemical nature of the various electrodes is responsible for such distinctive classification. Further work is to examine the capability of the electrochemical electronic tongues for semi-quantitative analyses of the metal salt concentration. |
| Starting Page | 446 |
| Ending Page | 449 |
| File Size | 743398 |
| Page Count | 4 |
| File Format | |
| ISBN | 9781457721397 |
| e-ISBN | 9781457721410 |
| DOI | 10.1109/NMDC.2011.6155403 |
| Language | English |
| Publisher | Institute of Electrical and Electronics Engineers, Inc. (IEEE) |
| Publisher Date | 2011-10-18 |
| Publisher Place | Korea (South) |
| Access Restriction | Subscribed |
| Rights Holder | Institute of Electrical and Electronics Engineers, Inc. (IEEE) |
| Subject Keyword | Radiation detectors Lead Zinc oxide Nickel Polymers Principal component analysis |
| Content Type | Text |
| Resource Type | Article |
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