NDLI: Chemical speciation at the liquid-liquid interface: Development of a time-resolved-spectroscopy induced by the evanescent wave of a laser beam

Content Provider	IEEE Xplore Digital Library
Author	Canto, F. Couston, L. Trong Hung Vu Charbonnel, M.-C.
Copyright Year	2009
Description	Author affiliation: CEA- DEN/Marcoule DRCP/SCPS/LCAM BP 17171 30207 BAGNOLS-sur-CEZE France (Canto, F.; Couston, L.; Trong Hung Vu; Charbonnel, M.-C.)
Abstract	Liquid-liquid extraction is essential to the spent nuclear fuel reprocessing industry, and future more efficient plants will require the development of increasingly selective chemical processes. Interactions between the actinides and organic ligands must be better understood for this purpose, particularly near liquid-liquid interfaces. We therefore undertook to develop a measuring instrument combining sensitivity and spatial localization for spectroscopic analysis of this particular zone. The standard nuclearization requirements concerning such instruments led us to develop a farfield optical system with the desired sensitivity, but its spatial localization potential was too adversely impacted by interface fluid movements. In the light of the experimental findings we have reexamined the measurement and nuclearization options.
Starting Page	1
Ending Page	6
File Size	615592
Page Count	6
File Format	PDF
ISBN	9781424452071
DOI	10.1109/ANIMMA.2009.5503794
Language	English
Publisher	Institute of Electrical and Electronics Engineers, Inc. (IEEE)
Publisher Date	2009-06-07
Publisher Place	France
Access Restriction	Subscribed
Rights Holder	Institute of Electrical and Electronics Engineers, Inc. (IEEE)
Subject Keyword	Chemical industry Spectroscopy Instruments Molecular Speciation Chemical lasers Chemical processes Laser beams Nuclear fuels Liquid-Liquid interface Evanescence wave Time-resolved Laser-Induced Fluorescence Particle measurements Fuel processing industries Standards development
Content Type	Text
Resource Type	Article

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