NDLI: Polarization effects in homo-binuclear and trinuclear iron complexes

Content Provider	IEEE Xplore Digital Library
Author	Bonardi, A. Capelletti, R. Pelizzi, C. Tarasconi, P.
Copyright Year	1991
Description	Author affiliation: Parma Univ., Italy (Bonardi, A.; Capelletti, R.; Pelizzi, C.; Tarasconi, P.)
Abstract	Polarization phenomena induced by adsorption and desorption of solvated molecules in a new class of homo-binuclear and trinuclear iron complexes were investigated by means of correlated TSDC and infrared (IR) absorption spectra. ((Fe(L)))/sub 2/Fe(CN)/sub 6/Cl-4H/sub 2/O (where L is a bis(acylhydrazone) of 2,6-diacetylpyridine) shows a typical behavior: the TSDC bands occurring in the as-prepared pellet at approximately 180 and approximately 290 K disappear whenever the sample is stored in dynamic vacuum and a new one grows at approximately 155 K. The subsequent exposure to moist atmosphere causes a partial recovery of the spectrum, suggesting that loosely bound water molecules are responsible for the polarization phenomena. The adsorption and desorption kinetics analyzed by means of IR spectroscopy supported such a conclusion.<>
Starting Page	123
Ending Page	128
File Size	225346
Page Count	6
File Format	PDF
ISBN	0780301129
DOI	10.1109/ISE.1991.167194
Language	English
Publisher	Institute of Electrical and Electronics Engineers, Inc. (IEEE)
Publisher Date	1991-09-25
Access Restriction	Subscribed
Rights Holder	Institute of Electrical and Electronics Engineers, Inc. (IEEE)
Subject Keyword	Polarization Iron Chemistry Physics Kinetic theory Spectroscopy Dielectrics Solids
Content Type	Text
Resource Type	Article

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