NDLI: Electron injection in electron-only devices based on a symmetric metal/silole/metal structure

Content Provider	IEEE Xplore Digital Library
Author	Palilis, L.C. Uchida, M. Kafafi, Z.H.
Copyright Year	1995
Abstract	We report on electron injection from two different metal electrodes into three silole derivatives, namely 2,5-di-(3-biphenyl)-1,1-dimethyl-3,4-diphenylsilacyclopentadiene (PPSPP), 1,2-bis(1-methyl-2,3,4,5,-tetraphenylsilacyclopentadienyl) ethane (2PSP) and 2,5-bis-(2', 2''-bipyridin-6-yl)-1, 1-dimethyl-3,4-diphenylsilacyclopentadiene (PyPySPyPy), previously employed as emissive and electron transport materials in molecular organic light-emitting diodes (MOLEDs). Silole films were sandwiched between symmetric Mg:Ag or bilayer CsF-Al electrodes. The steady-state current density-voltage characteristics were measured as a function of the silole layer thickness for the two cathodes. The trap-free space-charge-limited current based on time-of-flight measurements compared with the injected electron current for PyPySPyPy indicated that Mg:Ag contacts limit the injected current, while CsF-Al contacts behave as quasi-ohmic contacts. Similar findings were obtained for 2PSP and PPSPP allowing steady-state derived electron mobility parameters to be extracted. Based on space-charge-limited conduction analysis of the measured current-voltage characteristics, PyPySPyPy is found to be a superior electron transporting silole with approximately an order of magnitude higher electron mobility (2.0/spl times/10/sup -4/ cm/sup 2//Vs) compared with those of 2PSP (2.4/spl times/10/sup -5/ cm/sup 2//Vs) and PPSPP (5.2/spl times/10/sup -5/ cm/sup 2//Vs), which is significantly higher than that of the prototype electron transport material tris (8-hydroxyquinolinolato) aluminum (III) (Alq/sub 3/) (6.5/spl times/10/sup -7/ cm/sup 2//Vs) at 0.6 MV/cm.
Sponsorship	IEEE Lasers and Electro-Optics Society
Starting Page	79
Ending Page	88
Page Count	10
File Size	408386
File Format	PDF
ISSN	1077260X
Volume Number	10
Issue Number	1
Language	English
Publisher	Institute of Electrical and Electronics Engineers, Inc. (IEEE)
Publisher Date	2004-01-01
Publisher Place	U.S.A.
Access Restriction	One Nation One Subscription (ONOS)
Rights Holder	Institute of Electrical and Electronics Engineers, Inc. (IEEE)
Subject Keyword	Electron mobility Current measurement Electrodes Steady-state Inorganic materials Organic materials Organic light emitting diodes Density measurement Thickness measurement Cathodes
Content Type	Text
Resource Type	Article
Subject	Atomic and Molecular Physics, and Optics Electrical and Electronic Engineering

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