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Content Provider | IEEE Xplore Digital Library |
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Author | Moscoso-Londono, O. Muraca, D. de Oliveira, L.A.S. Pirota, K.R. Socolovsky, L.M. |
Copyright Year | 1965 |
Abstract | In this paper, we report a novel, nontoxic and environmentally friendly diffusion route to obtain superparamagnetic poly(vinyl alcohol) (PVA)/polyacrylic acid (PAA) coated- Fe3O4 ferrogels (D-PAA). Magnetic properties of these D-PAA ferrogels were compared with regular ones produced with noncoated magnetite nanoparticles (D-NC). Their morphological features were studied by SEM-FEG. Absorption tests were performed in order to assess diffusion of nanoparticles into the PVA-polymeric matrix. D-PAA samples exhibit better dispersion of the nanoparticles within polymeric matrix in comparison with D-NC samples. The effective diffusion coefficients (Deff) obtained, as well as the nature of the functional groups in question, suggests interactions between the PAA and PVA in D-PAA samples. In D-NC samples is presumed that the iron atoms in the surface of the nanoparticles act as Lewis acids and coordinates with molecules that donate lone-pair electrons. The results suggest a reduction in the magnetic interaction for the coated nanoparticles case, due to the improvement of the dispersion of the nanoparticles into the polymeric matrix. |
Sponsorship | IEEE Magnetics Society |
Starting Page | 4551 |
Ending Page | 4554 |
Page Count | 4 |
File Size | 1068311 |
File Format | |
ISSN | 00189464 |
Volume Number | 49 |
Issue Number | 8 |
Language | English |
Publisher | Institute of Electrical and Electronics Engineers, Inc. (IEEE) |
Publisher Date | 2013-08-01 |
Publisher Place | U.S.A. |
Access Restriction | One Nation One Subscription (ONOS) |
Rights Holder | Institute of Electrical and Electronics Engineers, Inc. (IEEE) |
Subject Keyword | Nanoparticles Magnetic hysteresis Temperature measurement Iron Magnetic resonance imaging Magnetization Polymers magnetic properties Ferrogels iron oxides magnetic nanoparticles |
Content Type | Text |
Resource Type | Article |
Subject | Electronic, Optical and Magnetic Materials Electrical and Electronic Engineering |
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