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Aligned single wall carbon nanotube polymer composites using an electric field
| Content Provider | NASA Technical Reports Server (NTRS) |
|---|---|
| Author | Sauti, Godfrey Banda, Sumanth Ounaies, Zoubeida Wiklinson, John Wise, Kristopher E. Lillehei, Peter T. Harrison, Joycelyn S. Park, Cheol |
| Copyright Year | 2005 |
| Description | While high shear alignment has been shown to improve the mechanical properties of single wall carbon nanotubes (SWNT)-polymer composites, it is difficult to control and often results in degradation of the electrical and dielectric properties of the composite. Here, we report a novel method to actively align SWNTs in a polymer matrix, which allows for control over the degree of alignment of SWNTs without the side effects of shear alignment. In this process, SWNTs are aligned via field-induced dipolar interactions among the nanotubes under an AC electric field in a liquid matrix followed by immobilization by photopolymerization while maintaining the electric field. Alignment of SWNTs was controlled as a function of magnitude, frequency, and application time of the applied electric field. The degree of SWNT alignment was assessed using optical microscopy and polarized Raman spectroscopy and the morphology of the aligned nanocomposites was investigated by high resolution scanning electron microscopy. The structure of the field induced aligned SWNTs is intrinsically different from that of shear aligned SWNTs. In the present work, SWNTs are not only aligned along the field, but also migrate laterally to form thick, aligned SWNT percolative columns between the electrodes. The actively aligned SWNTs amplify the electrical and dielectric properties in addition to improving the mechanical properties of the composite. All of these properties of the aligned nanocomposites exhibited anisotropic characteristics, which were controllable by tuning the applied field conditions. |
| File Size | 1666558 |
| Page Count | 32 |
| File Format | |
| Alternate Webpage(s) | http://archive.org/details/NASA_NTRS_Archive_20080015451 |
| Archival Resource Key | ark:/13960/t83j8f78v |
| Language | English |
| Publisher Date | 2005-01-01 |
| Access Restriction | Open |
| Subject Keyword | Nonmetallic Materials Scanning Electron Microscopy Polymer Matrix Composites Shear Electrical Properties Reinforcement Structures Carbon Nanotubes Conductivity Mechanical Properties Raman Spectroscopy Alignment Nanocomposites Anisotropy Electric Fields Ntrs Nasa Technical Reports Server (ntrs) Nasa Technical Reports Server Aerodynamics Aircraft Aerospace Engineering Aerospace Aeronautic Space Science |
| Content Type | Text |
| Resource Type | Article |
