NDLI: The production of polycyclic aromatic hydrocarbon anions in inert gas matrices doped with alkali metals. electronic absorption spectra of the pentacene anion (c22h14(-))

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The production of polycyclic aromatic hydrocarbon anions in inert gas matrices doped with alkali metals. electronic absorption spectra of the pentacene anion (c22h14(-))

Content Provider	NASA Technical Reports Server (NTRS)
Author	Salama, Farid Halasinski, Thomas M. Allamandola, Louis J. Hudgins, Douglas M.
Copyright Year	1999
Description	The absorption spectra of pentacene (C22H14) and its radical cation (C22H14(+)) and anion (C22H14(-)) isolated in inert-gas matrices of Ne, Ar, and Kr are reported from the ultraviolet to the near-infrared. The associated vibronic band systems and their spectroscopic assignments are discussed together with the physical and chemical conditions governing ion (and counterion) production in the solid matrix. In particular, the formation of isolated pentacene anions is found to be optimized in matrices doped with alkali metal (Na and K).
File Size	1234727
Page Count	30
File Format	PDF
Alternate Webpage(s)	http://archive.org/details/NASA_NTRS_Archive_20000081766
Archival Resource Key	ark:/13960/t9964gr09
Language	English
Publisher Date	1999-01-01
Access Restriction	Open
Subject Keyword	Inorganic, Organic And Physical Chemistry Combustion Chemistry Spectroscopy Alkali Metals Combustion Products Chemical Reactions Synthesis Chemistry Rare Gases Radicals Electronic Spectra Anions Polycyclic Aromatic Hydrocarbons Reaction Kinetics Cations Absorption Spectra Ntrs Nasa Technical Reports Server (ntrs) Nasa Technical Reports Server Aerodynamics Aircraft Aerospace Engineering Aerospace Aeronautic Space Science
Content Type	Text
Resource Type	Article

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