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Computation of kinetics for the hydrogen/oxygen system using the thermodynamic method
| Content Provider | NASA Technical Reports Server (NTRS) |
|---|---|
| Author | Marek, C. John |
| Copyright Year | 1996 |
| Description | A new method for predicting chemical rate constants using thermodynamics has been applied to the hydrogen/oxygen system. This method is based on using the gradient of the Gibbs free energy and a single proportionality constant D to determine the kinetic rate constants. Using this method the rate constants for any gas phase reaction can be computed from thermodynamic properties. A modified reaction set for the H/O system is determined. A11 of the third body efficiencies M are taken to be unity. Good agreement was obtained between the thermodynamic method and the experimental shock tube data. In addition, the hydrogen bromide experimental data presented in previous work is recomputed with M's of unity. |
| File Size | 907251 |
| Page Count | 22 |
| File Format | |
| Alternate Webpage(s) | http://archive.org/details/NASA_NTRS_Archive_19970002983 |
| Archival Resource Key | ark:/13960/t0ps2qg6j |
| Language | English |
| Publisher Date | 1996-10-01 |
| Access Restriction | Open |
| Subject Keyword | Aircraft Propulsion And Power Thermodynamics Temperature Dependence Oxygen Gibbs Free Energy Kinetic Equations Hydrogen Reaction Kinetics Hydroxyl Radicals Chemical Reactions Thermodynamic Properties Ntrs Nasa Technical Reports Server (ntrs) Nasa Technical Reports Server Aerodynamics Aircraft Aerospace Engineering Aerospace Aeronautic Space Science |
| Content Type | Text |
| Resource Type | Article |
