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Pt/sno2-based co-oxidation catalysts for long-life closed-cycle co2 lasers
| Content Provider | NASA Technical Reports Server (NTRS) |
|---|---|
| Author | Schryer, David R. Upchurch, Billy T. Vannorman, John D. Wood, George M. Hess, Robert V. Brown, Kenneth G. Brown, David R. Schryer, Jacqueline Sidney, Barry D. Miller, Irvin M. |
| Copyright Year | 1990 |
| Description | Noble-metal/tin-oxide based catalysts such as Pt/SnO2 have been shown to be good catalysts for the efficient oxidation of CO at or near room temperature. These catalysts require a reductive pretreatment and traces of hydrogen or water to exhibit their full activity. Addition of Palladium enhances the activity of these catalysts with about 15 to 20 percent Pt, 4 percent Pd, and the balance SnO2 being an optimum composition. Unfortunately, these catalysts presently exhibit significant decay due in part to CO2 retention, probably as a bicarbonate. Research on minimizing the decay in activity of these catalysts is currently in progress. A proposed mechanism of CO oxidation on Pt/SnO2-based catalysts has been developed and is discussed. |
| File Size | 765258 |
| Page Count | 16 |
| File Format | |
| Alternate Webpage(s) | http://archive.org/details/NASA_NTRS_Archive_19900015273 |
| Archival Resource Key | ark:/13960/t1hj1f20w |
| Language | English |
| Publisher Date | 1990-06-01 |
| Access Restriction | Open |
| Subject Keyword | Lasers And Masers Water Additives Catalysts Hydrogen Carbon Dioxide Closed Cycles Palladium Tin Oxides Platinum Reaction Kinetics Oxidation Chemical Composition Carbonates Pretreatment Room Temperature Carbon Dioxide Lasers Ntrs Nasa Technical Reports ServerĀ (ntrs) Nasa Technical Reports Server Aerodynamics Aircraft Aerospace Engineering Aerospace Aeronautic Space Science |
| Content Type | Text |
| Resource Type | Article |