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Semiclassical theory of electronically nonadiabatic transitions in molecular collision processes
| Content Provider | NASA Technical Reports Server (NTRS) |
|---|---|
| Author | Lam, K. S. George, T. F. |
| Copyright Year | 1979 |
| Description | An introductory account of the semiclassical theory of the S-matrix for molecular collision processes is presented, with special emphasis on electronically nonadiabatic transitions. This theory is based on the incorporation of classical mechanics with quantum superposition, and in practice makes use of the analytic continuation of classical mechanics into the complex space of time domain. The relevant concepts of molecular scattering theory and related dynamical models are described and the formalism is developed and illustrated with simple examples - collinear collision of the A+BC type. The theory is then extended to include the effects of laser-induced nonadiabatic transitions. Two bound continuum processes collisional ionization and collision-induced emission also amenable to the same general semiclassical treatment are discussed. |
| File Size | 2456819 |
| Page Count | 84 |
| File Format | |
| Alternate Webpage(s) | http://archive.org/details/NASA_NTRS_Archive_19790019773 |
| Archival Resource Key | ark:/13960/t51g5h622 |
| Language | English |
| Publisher Date | 1979-01-01 |
| Access Restriction | Open |
| Subject Keyword | Atomic And Molecular Physics Transition Probabilities Classical Mechanics Ionization Scattering Cross Sections Quantum Mechanics Dipole Moments S Matrix Theory Nonadiabatic Conditions Electron Transitions Molecular Collisions Laser Applications Ntrs Nasa Technical Reports Server (ntrs) Nasa Technical Reports Server Aerodynamics Aircraft Aerospace Engineering Aerospace Aeronautic Space Science |
| Content Type | Text |
| Resource Type | Article |