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Esr studies of the slow tumbling of vanadyl spin probes in nematic liquid crystals
| Content Provider | NASA Technical Reports Server (NTRS) |
|---|---|
| Author | Lawson, J. O. Eastman, M. P. Bruno, G. V. |
| Copyright Year | 1977 |
| Description | ESR line shapes that are appropriate for slowly tumbling vanadyl spin probes in viscous nematic liquid crystals were calculated by the stochastic Liouville method. Because of the symmetry possessed by vanadyl, the analysis and interpretation of these line shapes was simplified considerably. Spectral line shapes agreed well with experimental spectra of VOAcAc in the nematic liquid crystal Phase V and BEPC. Deviations from Brownian rotational diffusion were noted. A slowly fluctuating torque analysis yielded good agreement with the experimental spectra. |
| File Size | 904841 |
| Page Count | 16 |
| File Format | |
| Alternate Webpage(s) | http://archive.org/details/NASA_NTRS_Archive_19770017022 |
| Archival Resource Key | ark:/13960/t9m37mh2p |
| Language | English |
| Publisher Date | 1977-03-01 |
| Access Restriction | Open |
| Subject Keyword | Solid-state Physics Liouville Theorem Tumbling Motion Vanadyl Compounds Mathematical Models Electron Paramagnetic Resonance Line Spectra Brownian Movements Liquid Crystals Probes Ntrs Nasa Technical Reports Server (ntrs) Nasa Technical Reports Server Aerodynamics Aircraft Aerospace Engineering Aerospace Aeronautic Space Science |
| Content Type | Text |
| Resource Type | Technical Report |