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A study of the effects of solid phase reactions on the thermal degradation and ballistic properties of solid propellants
| Content Provider | NASA Technical Reports Server (NTRS) |
|---|---|
| Author | Schmidt, W. G. |
| Copyright Year | 1974 |
| Description | The thermal stability of perchlorate composite propellants was studied at 135 and 170 C. The experimental efforts were concentrated on determining the importance of heterogeneous oxidizer-fuel reactions in the thermal degradation process. The experimental approach used to elucidate the mechanisms by which the oxidizer fuel composites thermally degrade was divided into two parts: (1) keeping the fuel constant and varying the nature of the oxidizers, and (2) holding the oxidizer constant and varying the fuel components. The fuel component primarily utilized in the first phase was polyethylene. Oxidizers included KClO4, KClO3, NH4ClO4 and NH4ClO4 doped with materials such as chlorate, phosphate and arsenate. In the second phase the oxidizer used was primarily NH4ClO4 while the fuels included saturated and unsaturated polybutadiene prepolymers and a series of bonding agents. Techniques employed in the current study include thermogravimetric measurements, differential thermal analysis, infrared, mass spectrometry, electron microscopy, and appropriate wet chemical analysis. |
| File Size | 6847311 |
| Page Count | 55 |
| File Format | |
| Alternate Webpage(s) | http://archive.org/details/NASA_NTRS_Archive_19740009382 |
| Archival Resource Key | ark:/13960/t1tf4k753 |
| Language | English |
| Publisher Date | 1974-02-01 |
| Access Restriction | Open |
| Subject Keyword | Propellants Polyethylenes Potassium Perchlorates Composite Propellants Thermogravimetry Mass Spectroscopy Perchlorates Thermal Stability Nitronium Perchlorate Oxidizers Thermal Degradation Ntrs Nasa Technical Reports Server (ntrs) Nasa Technical Reports Server Aerodynamics Aircraft Aerospace Engineering Aerospace Aeronautic Space Science |
| Content Type | Text |
| Resource Type | Technical Report |