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Tetraperchlorate of methane
| Content Provider | NASA Technical Reports Server (NTRS) |
|---|---|
| Author | Schack, C. J. |
| Copyright Year | 1972 |
| Description | The preparation of the tetraperchlorate of methane (TPM) was attempted. Displacement of halogen from carbon tetrahalides was accomplished with either CCl4 or CBr4 using the halogen perchlorates, ClOClO3, and BOClO3. Although the displacement process was successful, the generated carbon perchlorate intermediates were not isolated. Instead, these species decomposed to COCl2, CO2, and Cl2O7. The vigorous displacement reaction that often occurred required moderation. Fluorocarbon solvents and chlorine perchlorate were successfully tested for compatibility, permitting their use in these synthetic reactions. While the sought for moderating effect was obtained, the net result of the displacement of halogen from CX sub 4 substrates was the same as before. Thus only CO2, COCl2, and Cl2O7 were isolated. |
| File Size | 882939 |
| Page Count | 28 |
| File Format | |
| Alternate Webpage(s) | http://archive.org/details/NASA_NTRS_Archive_19730002379 |
| Archival Resource Key | ark:/13960/t4bp4v51g |
| Language | English |
| Publisher Date | 1972-05-30 |
| Access Restriction | Open |
| Subject Keyword | Chemistry Methane Synthesis Halides Halogen Compounds Carbon Tetrachloride Chemical Reactions Oxidation Perchlorates Ntrs Nasa Technical Reports Server (ntrs) Nasa Technical Reports Server Aerodynamics Aircraft Aerospace Engineering Aerospace Aeronautic Space Science |
| Content Type | Text |
| Resource Type | Technical Report |
