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Lead(II): Lewis acid and occasional base, as illustrated by its complex with 1,5-naphthalenedisulfonate and 5-methyl-1,10-phenanthroline
| Content Provider | Hyper Articles en Ligne (HAL) |
|---|---|
| Author | Harrowfield, Jack Thuéry, Pierre |
| Abstract | A crystal structure determination of the Pb(II) coordination polymer [Pb(Mephen)(1,5-nds)(H2O)]n provides not only evidence of the common action of Pb(II) as a Lewis acid but also clear proof of its ability, in the solid state at least, to act as a Lewis base. This action as a base is attributed to the presence of a valence shell lone pair and its identification here is further evidence for the occasional but not universally detectable influence of the lone pair on the metal ion stereochemistry. |
| Related Links | https://cea.hal.science/cea-01573207/file/DaltonTrans_Thuery082017_V0.pdf |
| ISSN | 14779226 |
| e-ISSN | 14779234 |
| DOI | 10.1039/C7DT01975K |
| Journal | Dalton Transactions |
| Volume Number | 46 |
| Language | English |
| Publisher | HAL CCSD Royal Society of Chemistry |
| Publisher Date | 2017-08-07 |
| Access Restriction | Open |
| Subject Keyword | Material chemistry Chemical Sciences |
| Content Type | Text |
| Resource Type | Article |
| Subject | Chemical Engineering Inorganic Chemistry |